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Data bank of environmental chemicals     |     The Finnish Environment Institute (SYKE)
 


26.4.2024

Data bank of environmental properties of chemicals


Chemical
Cadmium nitrate
CAS-number :
10325-94-7
 
Synonyms :
cadmium dinitrate.
Kadmiumnitraatti
nitric acid, cadmium salt
 
Sumformula of the chemical :
CdN2O6 * Cd(NO3)2
EINECS-number :
2337106
 
Uses :
Colouring glass and porcelain; laboratory reagent; cadmium
salts. 
Photographic emulsions. 
Manufacturing light sensitive
paper; chemicals production Ni-Cd batteries.
 
State and appearance :
Prismatic white needles; hygroscopic.
 
Molecular weight :
236.42
 
Vapor density (air=1) :
2.455 
 
Water solubility, mg/l :
1500000  20 °C, Anon. 1989
 
Melting point, °C :
350 
 
Boiling point, °C :
132 
 
Other information of degradation :
Natural CO2 will slowly reduce concentration (Sax 1986).
 
Other information of metabolism :
Cd content of livers and kidneys increased in direct proportion
to intake. 
Kidneys retained 2 - 3 times the amount retained by
the liver. 
Shellfish concentration Cd 900 - 1600 times (Sax
1986).
 
Health effects :
Emphysema from Cd salt dusts, itai-itai disease (Sax 1986).

Strong irritant. 
Affects central nervous system. 
Poor warning
properties. 
Cadmium salts cause cramps, nausea, vomiting and
diarrhea. 
Inflammation of mucous membrane. 
Headache. 
Oral
ingestion has led to a number of human deaths. 
Acute poisoning
causes lung damage; chronic poisoning damages kidneys, lungs,
bones, causes blood changes. 
Symptoms include dark urine,
dyspnea, chest pain (Sax 1986).
 
Effects on plants :
Soybean, tomato, bushbean, and bahia grass plants were exposed to
0.1 g Cd per 6 or 7 inch pot (15 - 17 cm). 
The general
symptoms included a red-brown discoloration of leaf veins,
petioles and stems. 
Leaves cupped and rolled downward with
puckering of intercostal laminae. 
Tomato leaves developed
interveinal chlorosis and necrotic flecking, and yield
reductions were observed. 
Iron foliar content decreased with
increased Cd application in bahia grass and soybean. 
Manganese
content decreased, due to increased Cd application in bahia
grass but not in soybean (Sax 1986).
 
Effects on microorganisms :
Toxicity threshold (cell multiplication inhibition test):
bacteria (Pseudomonas putida): 0.08 mg/l
(Bringmann & Kühn 1980a)
 
NOEC values to algae, mg/l :
0.7  rpd,schr, Selenastrum capricornutum,
  Slooff et al. 1983
 
LC50 values to crustaceans, mg/l :
0.047  48 hr, Daphnia magna
0.14  48 hr, Daphnia pulex
0.2  48 hr, Daphnia cucullata
  Canton & Adema 1978
  --
0.5  48hr, Asellus aquaticus, Slooff 1983
0.08  48hr, Gammarus pulex, Slooff 1983
 
EC50 values to crustaceans, mg/l :
0.078  96hr, Homarus americanus
0.14  48hr, Daphnia pulex
0.2  48hr, Daphnia cucullata
0.042  0.042 - 0.055, 48hr, Daphnia magna
0.055  Sax 1986
 
LC50 values to fishes, mg/l :
0.15  48 hr, Salmo gairdneri
  Slooff et al. 1983
  --
0.056  Cd, act, Poecilia reticulata, Sax 1986
0.0066  Cd, 96hr, Salmo gairdneri
  --
0.0066  96hr, flow-through, Salmo gairdneri
  Hale 1977
 
Effects on physiology of water organisms :
Selenastrum capricornutum, 0.13 - 4 days, 0.002 - 0.004 mg/l;
growth effect (measurable change in length and/or weight
(Thompson et al. 1987).

Cyprinus carpio, hematological effect, 3.75 d, 11 mg/l (Beena &
Viswaranjan 1988).

Lamellidens marginalis, physiological effect, 1 d, 2 mg/l
(Radhakrishnaiah 1988).

Selenastrum capricornutum, population growth effect,
photosynthesis effect, 4 d, 0.002 - 0.008 mg/l (Thompson et al.
1987).

Tilapia aurea, growth effect, mortality, 112 d, 0.014 - 0.052
mg/l (Papoutsoglou & Abel 1988).
 
Other information of water organisms :
2.7 mg/l, flatworm (Polycelis nigra), toxic threshold
concentration. -  0.42 mg/l, stickleback, toxic threshold
concentration. -  0.2 mg/l as Cd, stickleback, lethal
concentration limit, 15 - 18 °C. -  0.7 mg/l as Cd,
stickleback, survived. -  0.056 mg/l as Cd, guppy, LD50 (Sax
1986).

LC50, 48hr, 6.5 mg/l, Tubificidae
LC50, 48hr, >56 mg/l, Chironomus gr. thummi
LC50, 48hr, 4.2 mg/l, Erpobdella octoculata
LC50, 48hr, 1.6 mg/l, Lymnaea stagnalis
LC50, 48hr, >56 mg/l, Dugesia cf. lugubris
LC50, 48hr, 1.6 mg/l, Hydra oligactis
LC50, 48hr, >56 mg/l, Corixa punctata
LC50, 48hr, >56 mg/l, Ischura elegans
LC50, 48hr, 49 mg/l, Nemoura cinerea
LC50, 48hr, 56 mg/l, Cloeon dipterum
(Slooff 1983)

Toxicity threshold (cell multiplication inhibition test):
green algae (Scenedesmus quadricauda): 0.031 mg/l
protozoa (Entosiphon sulcatum): 0.011 mg/l
(Bringmann & Kühn 1980a)
 
Other information :
Air pollution: high (Sax 1986).

References
2285Anon. 1989. Miljöfarliga ämnen - exempellista och vetenskaplig dokumentation. 303 p. Stockholm. Rapport från kemikalieinspektionen (KEMI) 10.
2298Beena, S. & Viswaranjan, S. 1988. Effect of cadmium and mercury on the hematological parameters of the fish Cyprinus carpio. Environ. Ecol. 5: 726.
188Bringmann, G. & Kühn, R. 1980a. Comparison of the toxicity thresholds of water pollutants to bacteria, algae and protozoa in the cell multiplication inhibition test. Water Res. 14: 231 - 241.
241Canton, J.H. & Adema, D.M.M. 1978. Reproducibility of short-term and reproduction toxicity experiments with Daphnia magna and comparisons of the sensitivity of Daphnia magna with Daphnia pulex and Daphnia cucullata in short-term experiments. Hydrobiologia 59(2): 135 - 140.
522Hale, J.G. 1977. Toxicity of metal mining wastes. Bull. Environ. Contam. Toxicol. 17: 66.
2301Papoutsoglou, S.E. & Abel, P.D. 1988. Sublethal toxicity and accumulation of cadmium in Tilapia aurea. Bull. Environ. Contam. Toxicol. 41: 404.
2299Radhakrishnaiah, K. 1988. Effect of cadmium on the freshwater mussel, Lamellidens marginalis (Lamarck) - A Physiologial approach. J. Environ. Biol. 9: 73.
2147Sax, I. 1986. Hazardous chemicals information annual No. 1. Van Nostrand Reinhold Information Services, New York. 766 s.
1304Slooff, W., Canton, J.H. & Hermens, J.L.M. 1983. Comparison of the susceptibility of 22 freshwater species to 15 chemical compounds. I (sub)acute toxicity tests. - Aquatic toxicology 4: 113 - 128.
1302Slooff, W. 1983. Benthic macroinvertebrates and water quality assessment: some toxicological considerations. Aquat. Toxicol. 4: 73.
1948Thompson, P.A. et al. 1987. Structure-function relationships for monitoring cellular stress and recovery responses with Selenastrum capricornutum. Aquat. Toxicol. 10: 291.
2300Thompson, P.A. et al. 1987. Structure-function relationships for monitoring cellurar stress and recovery responses with Selenastrum capricornutum. Aquat. Toxicol. 10: 291.

 
 
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