www.ymparisto.fi
 
 
Data bank of environmental chemicals     |     The Finnish Environment Institute (SYKE)
 


11.5.2024

Data bank of environmental properties of chemicals


Chemical
Benzaldehyde
CAS-number :
100-52-7
 
Synonyms :
Bentsaldehydi
benzenecarbonal
oil of bitter almonds.
 
Sumformula of the chemical :
C7H6O
EINECS-number :
2028604
 
Odor :
Characteristic: quality: bitter almonds.
 
Molecular weight :
106.13
 
Spesicif gravity (water=1) :
1.05  at 15/4 °C
 
Vapor density (air=1) :
3.66 
 
Conversion factor, 1 ppm in air=_mg/m3 :
4.41  mg/m3
 
Conversion factor, 1 mg/m3 in air=_ppm :
0.227  ppm
 
Vapor pressure, mmHg :
26°C
40  90 °C
 
Water solubility, mg/l :
3300 
5000  MITI 1992
 
Melting point, °C :
-25 
 
Boiling point, °C :
179 
179  MITI 1992
 
Log octanol/water coefficient, log Pow :
1.48 
1.48  Sangster 1989
 
Total degradation in water :
Biodegradation:
66% by BOD
period: 14d
substance: 100 mg/l
sludge: 30 mg/l
(MITI 1992)
 
Ready biodegradability :
Confirmed to be biodegradable (Anon. 1987).
 
LD50 values to mammals in oral exposure, mg/kg :
1300  orl-rat, Lewis & Sweet 1984
28  orl-mus, - " -
 
LD50 values to mammals in non-oral exposure , mg/kg :
5000  scu-rbt, Patty 1967
 
Effects on microorganisms :
Toxicity threshold (cell multiplication inhibition test):
Bacteria (Pseudomonas putida): 132 mg/l (Bringmann & Kühn 1980a)
 
LC50 values to crustaceans, mg/l :
15.8  >15.8, 96hr, Orconectes nais
  Phipps & Holcombe 1985
 
LC50 values to fishes, mg/l :
11.2  srv, act, 96 hr, Salmo gairdneri,
1.07  srv, act, 96 hr, Lepomis macrochirus,
12.4  96hr, Pimephales promelas
13.8  96hr, Carassius auratus
5.39  96hr, Ictalurus punctatus
  Phipps & Holcombe 1985
  --
1.269  4d, Salmo gairdneri, McKim et al. 1987
  --
7.61  96 hr, Pimephales promelas, Brooke et al. 1984
  --
12.8  96 hr, Pimephales promelas, Geiger et al. 1985
 
EC50 values to fishes, mg/l :
6.61  96 hr, mbt, Pimephales promelas, Brooke et al. 1984
 
Other information of water organisms :
Toxicity threshold (cell multiplication inhibition test):
algae (Microcystis aeruginosa): 20 mg/l (Bringmann & Kühn 1976)
green algae (Scenedesmus quadricauda): 34 mg/l (Bringmann & Kühn
protozoa (Entosiphon sulcatum): 0.29 mg/l       1980a)
protozoa (Uronema parduczi): 22 mg/l (Verschueren 1983)

Fish: minnows: stop eating: 17.1 mg/l of 85 % solution
(McKee & Wolf 1963).

Lethal threshold concentration (LT50): 3.79 mg/l, 0.8d (McKim et
al. 1987).

LC50, >15,8 mg/l, 96hr, snail, Phipps & Holcombe 1985

References
1848Anon. 1987a. The list of the existing chemical substances tested on biodegradability by microorganisms or bioaccumulation in fish body by Chemicals Inspection & Testing Institute. Ministry of International Trade and Industry, MITI. Japan.
187Bringmann, G. & Kühn, R. 1976. Vergleichende Befunde der Schadwirkung wassergefährdender Stoffe gegen Bakterien (Pseudomonas putida) und Blaualgen (Microcystis aeruginosa). Gwf-Wasser-Abwasser 117(9).
188Bringmann, G. & Kühn, R. 1980a. Comparison of the toxicity thresholds of water pollutants to bacteria, algae and protozoa in the cell multiplication inhibition test. Water Res. 14: 231 - 241.
3295Brooke, L. T. et al. 1984. Acute toxicities of organic chemicals to fathead minnows (Pimephales promelas); Vol 1. Center for Lake Superior Environmental Studies University of Wisconsin-Superior, Superior, Wisconsin, U.S.A.
3296Geiger, D. L. et al. 1985. Acute toxicities of organic chemicals to fathead minnows (Pimephales promelas) Vol. 2. Center for Lake Superior Environmental Studies, University of Wisconsin-Superior, Superior, Winconsin, U.S.A. 326.
1589Lewis, R.J. & Sweet, D.V. 1984. Registry of toxic effects of chemical substances. National Institute for Occupational Safety and Health. No. 83-107-4.
921McKee, J.W. & Wolf, H.W. 1963. Water quality criteria. The Resources Agency of California, State Water Quality Control Board.
1899McKim, J.M. et al. 1987b. Use of respiratory-cardiovascular responses of rainbow trout (Salmo gairdneri) in identifying acute toxicity syndromes in fish. Part 2. Malathion, carbaryl, acrolein and benzaldehyde. Environ. Toxicol. Chem. 6: 313.
3105MITI 1992. Biodegradation and bioaccumulation data of existing chemicals based on the CSCL Japan. Compild under the Safety Division Basic Industries Bureau Ministry of International Trade & Industry, Japan. Edited by Chemicals Inspection & Testing Institute, Japan.
1644Patty, F.A. 1967. Industrial hygiene and toxicology. Vol 2. Interscience Publishers.
1123Phipps, G.L. & Holcombe, G.W. 1985. A method for multiple species toxicant testing: acute toxicity of 10 chemicals to 5 vertebrates and 2 invertebrates. Environm. Pollut. (Ser A) 38: 141 - 157.
3104Sangster, J. 1989. Octanol-water partition coefficients of simple organic compounds. J. Phys. Chem. Ref. Data, Vol 18, No. 3: 1111 - 1229.
1468Verschueren, K. 1983. Handbook of environmental data of organic chemicals. Van Nostrand Reinhold Co. Inc., New York. 1310 s.

 
 
© Copyright Environmental Administration