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Data bank of environmental chemicals     |     The Finnish Environment Institute (SYKE)
 


20.4.2024

Data bank of environmental properties of chemicals


Chemical
Lead
CAS-number :
7439-92-1
 
Synonyms :
Lyijy
 
Sumformula of the chemical :
Pb
EINECS-number :
2311004
 
Uses :
Accumulator manufacturing; antiknock combounds for gasoline;
brass manufacturing; cable mantles; anticorrosive pigment (red
lead; chrome yellow; white lead); organic lead compounds
(additive in colours).
 
Molecular weight :
207.19
 
Mobility :
Relatively unsoluble lead sulfate, lead phosphate and lead
carbonate is formed in soil. 
Adsorption to clay minerals, Fe-
and Mn-oxides decreases also mobility of Pb. 
In acid soils Pb
is strongly complexed with organic material (Kabata-Pendias &
Pendias 1984).

In water environment Pb is mainly complexed or adsorbed to
particular material and sediment (Kabata-Pendias & Pendias
1984).
 
Other information of metabolism :
Pb is excreted via urine and feces (Grandjean & Nielsen 1979).
 
TDLo values to mammals in oral exposure, mg/kg :
450  6yr,orl-wmn,Lewis & Sweet 1984
 
TCLo values to mammals in inhalation exposure, mg/kg :
0.01  ihl-hmn,Lewis & Sweet 1984
 
Effects on physiology of mammals :
Rats exposed to 0.011 mg inorganic Pb/m3 in air for 6 hours per
day for 3 months showed changes in behaviour (Waldron & Stöfen
1974).
 
Health effects :
Inhibition of growth, disorders in nervous system, impaired
resistence to infections; genetic damages etc. in mammals
(Folkesson 1976).
 
Carcinogenicity :
Chronic lead poisoning can cause tumours in kidneys (Waldron &
Stöfen 1974).
 
LDLo values to birds in oral exposure, mg/kg :
160  orl-pgn,Lewis & Sweet 1984
 
Effects on amphibia :
LC50 (96hr), 33.28 ppm, tadpoles of Rana hexadactyla (Khangarot
et al. 1985).
 
Effects on plants :
18.8 mg Pb/kg of dry matter (upper critical tissue
concentration for sitka-spruce (Picea sitchensis) seedlings;
concentration above which yields are reduced because of toxic
effects (Burton et al. 1983).

Diethyllead dichloride: 0.0000001 mol/l, 24hr,Spindle
disturbances; Triethyllead chloride : 0.0000001 mol/l, 6hr,
mitotic changes; Dimethyllead dichloride: 0.0000001 mol/l,
24hr  index (Allium cepa); Trimethyllead chloride: 0.000001
mol/l, 6hr    (Ahlberg et al. 1972)
Lead nitrate: 10-4 mol/l, 6hr

Young plantlets of lettuce (Lactuva sativa) were influenced by
tetramethyl lead in the form of water solutions (0.001 %) for
0 - 24 hours -> in the rootcells following organels are damaged;
the nucleus, the mitochondria, the Golgi apparatus, the
endoplasmic reticulum and the proplastids; disturbances of cell
division (Sekerka & Bobak 1974).
 
EC50 values to algae, mg/l :
0.14  rpd, schr, Selenastrum capricornutum
  Christensen et al. 1979
  --
11  96hr, rpd, Navicula incerta
  Rachlin et al. 1983
 
LC50 values to crustaceans, mg/l :
0.3  21d, Daphnia magna
0.45  48hr, with food, Daphnia magna
  Biesinger & Christensen 1972
  --
64.1  96hr, mbt, Asellus aquaticus
120  48hr, mbt, Asellus aquaticus
  Martin & Holdich 1986
 
EC50 values to crustaceans, mg/l :
0.1  21d, rpd, Daphnia magna
  Biesinger & Christensen 1972
 
LOEC values to crustaceans, mg/l :
0.03  rpd, 21d, Daphnia magna,
  Biesinger & Christensen 1972
 
LC50 values to fishes, mg/l :
0.22  28d,Salmo gairdneri
  Birge et al. 1980
  --
26  96hr, Colisa fasciata
  Saxena & Parashari 1983
  --
19  96hr, Channa punctata
  Srivastava & Mishra 1979
 
LOEC values to fishes, mg/l :
0.0007  srv, chr, Salmo gairdneri
0.032  rpd, grw, chr, Salmo gairdneri
  Davies et al. 1976
  --
0.084  srv, grw, chr, Salvelinus fontinalis
  Holcombe et al. 1976
  --
0.062  rpd, chr, Platichthys flesus
  McKim 1977
 
NOEC values to fishes, mg/l :
0.0004  srv, chr, Salmo gairdneri
0.018  rpd, grw, chr, Salmo gairdneri
  Davies et al. 1976
  --
0.039  srv, grw, chr, Salvelinus fontinalis
  Holcombe et al. 1976
  --
0.031  rpd, chr, Platichthys flesus
  McKim 1977

References
1721Ahlberg, L., Ramel, C. & Wachtmeister, C.A. 1972. Organolead compounds shown to be genetically active. Ambio 1(1): 29 - 31.
2285Anon. 1989. Miljöfarliga ämnen - exempellista och vetenskaplig dokumentation. 303 p. Stockholm. Rapport från kemikalieinspektionen (KEMI) 10.
139Biesinger, K.E. & Christensen, G.M. 1972. Effects of various metals on survival, growth, reproduction, and metabolism of Daphnia magna. J. Fish. Res. Board Can. 29: 1691 - 1700.
149Birge, W.J. et al. 1980. Aquatic toxicity tests on inorganic elements occuring in oil shale. EPA 600/9-80-022. NTIS, Dep. of Commerce, Springfield, Va.
1720Burton, K.W., Morgan, E. & Roig, A. 1983. The influence of heavy metals upon the growth of sitka-spruce in South Wales forests. I. Upper critical and foliar concentrations. Plant and Soil 73: 327 - 336.
268Christensen, E.R. & Scherfig, S. & Dixon, P.S. 1979. Effects of manganese, copper and lead on Selenastrum capricornutum and Chlorella stigmatophora. Water Res. 13: 79 - 92.
318Davies, P.H., Goettl, J.P., Sinley, J.R. & Smith, N.F. 1976. Acute and chronic toxicity of lead to rainbow trout Salmo gairdneri in hard and soft water. Water Res. 10: 199 - 206.
2551Folkeson, L. 1976. Bly, särskilt avgasbly, i den terrestra miljön. SNV PM 794.
2547Grandjean, P. & Nielsen, T. 1979. Organolead compounds: Environmental health aspects. Residue Rev. 72: 97 - 148.
591Holcombe, G.W., Benoit, D.A., Leonard, E.N. & McKim, J.M. 1976. Long-term effects of lead exposure on three generations of brook trout. J. Fish. Res. Board Can. 33: 1731 - 1741.
2541Kabata-Pendias, A. & Pendias, H. 1984. Trace elements in soils and plants. CRC Press, Inc. Boca Raton, Florida.
1767Khangarot, B.S., Sehgal, A. & Bhasin, E.K. 1985. Man and biosphere - Studies on the Sikkim Himalayas. Part 5: Acute toxicity of selected heavy metals on the tadpoles of Rana hexadactyla. Acta hydrochim. et hydrobiol. 13(2): 259 - 263.
1768Khangarot, B.S., Sehgal, A. & Bhasin, M.K. 1985. Man and Biosphere - Studies on the Sikkim Himalayas. Part 6: Toxicity of selected pesticides to frog tadpole Rana hexadactyla (Lesson). Acta hydrochim. hydrobiol. 13(3): 391 - 394.
1589Lewis, R.J. & Sweet, D.V. 1984. Registry of toxic effects of chemical substances. National Institute for Occupational Safety and Health. No. 83-107-4.
1763Martin, T.R. & Holdich, D.M. 1986. The acute lethal toxicity of heavy metals to peracarid crustaceans (with particular reference to fresh-water asellids and gammarids). Water Res. 20(9): 1137 - 1147.
924McKim, J.M. 1977. Evaluation of tests with the early life stages of fish for predicting long term toxicity. J. Fish. Res. Board Can. 34: 1148 - 1154.
1973Pilli.A., Carle, D.O., Kline. E., Pickering. Q. & Lazorchak. J. 1988. Effets of pollution on freshwater organisms. JWPCF 60(6): 994 - 1065.
2540Piotrowski, J.K. & Coleman, D.O. 1980. Environmental hazards of heavy metals: Summary evaluation of lead, cadmium and mercury. MARC Report No. 20, Chelsea College, University of London.
1147Rachlin, J.W. et al. 1983. The growth response of the diatom Navicula incerta to selected concentrations of the metals: cadmium, copper, lead and zinc. Bull. Torrey Bot. Club. 110: 217.
1235Saxena, O.P. & Parashari, A. 1983. Comparative study of the toxicity of six heavy metals to Channa punctatus. J. Environ. Biol. 4: 91.
1722Sekarka, V. & Bobák, M. 1974. Influence of lead upon the plant cell. Acta F. R. N. Univ. Comen. - Physiologia Plantarum IX: 1 - 12.
1358Srivastava, A.K. & Mishra, S. 1979. Blood dyscrasia in a teleost fish, Colisa fasciatus, associated with cadmium poisoning. J. Comp. Pathol. 89: 609.
2552Waldron, H.A. & Stöfen, D. 1974. Sub-clinical lead poisoning. A.P.

 
 
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