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Data bank of environmental chemicals     |     The Finnish Environment Institute (SYKE)
 


26.4.2024

Data bank of environmental properties of chemicals


Chemical
Ethylene
CAS-number :
74-85-1
 
Synonyms :
ethene
etyleeni
 
Sumformula of the chemical :
C2H4
EINECS-number :
2008153
 
Odor :
Quality: olefinic
Hedonic tone: unpleasant to neutral
Threshold odour concentration
absolute: 260 ppm
50 % recognition: 400 ppm
100 % recognition: 700 ppm
Odour index 100 % recognition: 1 428
(Hellman & Small 1974)
 
Molecular weight :
28.05
 
Melting point, °C :
-169 
 
Boiling point, °C :
-103.7 
 
Henry's law constant, Pa x m3/mol :
21030  calc. Yaws et al. 1991
 
Photochemical degradation in air :
Photooxidation half-life in air:
6.2hr - 56hr,
bsed upon combined, measured photooxidation rate constants for  -
OH and ozone (Howard 1991).
 
Photochemical degradation in water :
Photooxidation half-life in water:
80d - 3200d,
based upon a measured rate constant for reaction with -OH in 
aqueous solution (Howard 1991).
 
Half-life in air, days :
0.3  6.2hr - 56hr,
2.3  based upon combined, measured photooxidation
  rate constant for -OH and ozone,
  Howard 1991
 
Half-life in soil, days :
1d - 4w,
28  scientific judgement based upon biological
  screening tests in soil,
  Howard 1991
 
Half-life in water, days :
1d - 4w,
28  in surface water, scientific judgement based upon
  soil biodegradation half-lives,
2d - 8w,
56  in ground water, scientific judgement based upon
  soil biodegradation half-lives,
  Howard 1991
 
Aerobic degradation in water :
Aerobic half-life:
4d - 16w, 
scientific judgement based upon soil biodegradation half-lives 
(Howard 1991).
 
Effects on plants :
0.002 - 0.02 ppm (0.0023 - 0.023 mg/m3) for 24 (nonwoody plants
susceptible to ethylene) (U.S. 
Environmental Protection Agency
1976).

References
1673Hellman, T.M. & Small, F.H. 1974. Characterization of the odour properties of 101 petrochemicals using sensory methods. J. Air Pollut. Control Assoc. 24: 979 - 982.
3120Howard, P.H., Boethling, R.S., Jarvis, W.F., Meylan, W.M. & Michalenko, E.M., Handbook of Environmental Degradation Rates, 1991. Lewis Publicers, Inc., Chelsea, Michigan, U.S.A., pp. 725.
1121U.S. Environmental Protection Agency. 1976. Diagnosing vegetation injury caused by air pollution. U.S.E.P.A., Washingron, D.C.
3030Yaws, C., Yang, H-C. & Pan, X. 1991. Henry's law constants for 362 organic compounds in water. Chemical Engineering. November. p 179 - 185.

 
 
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