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Data bank of environmental chemicals     |     The Finnish Environment Institute (SYKE)
 


19.4.2024

Data bank of environmental properties of chemicals


Chemical
Silver nitrate
CAS-number :
7761-88-8
 
Synonyms :
Hopeanitraatti.
Nitric acid silver(1+) salt
 
Sumformula of the chemical :
AgNO3 Ag.HNO3
EINECS-number :
2318539
 
Uses :
Photographic film, catalyst for ethylene oxide, indelible inks,
silver plating, silver salts, silvering mirrors, germicide (as a
wall spray), hair dyeing, antiseptic, fused form to cauterize
wounds, lab reagent.
 
State and appearance :
Colorless, transparent, tabular, rhombic crystals becoming gray
or grayish-black on exposure to light in the presence of
organic matter.
 
Odor :
Odorless; bitter, caustic metallic taste.
 
Molecular weight :
169.88
 
Water solubility, mg/l :
2160000  25 °C
 
Melting point, °C :
212 
 
Degradation point, °C :
444 
 
LD50 values to mammals in oral exposure, mg/kg :
50  orl-mus, Lewis & Sweet 1984
  --
129  orl-mus, Christensen 1973
 
LD50 values to mammals in non-oral exposure , mg/kg :
34.5  ipr-mus, Sax & Lewis 1989
 
LDLo values to mammals in oral exposure, mg/kg :
20  orl-dog, Lewis & Sweet 1984
  --
800  orl-rbt, Sax & Lewis 1989
 
LDLo values to mammals in non-oral exposure , mg/kg :
8.8  ivn-rbt, Sax & Lewis 1989
216  ipr-gpg,
62  scu-gpg,
 
TDLo values to mammals in non-oral exposure , mg/kg :
13.59  scu-rat, Sax & Lewis 1989
50  scu-dog,
15000  skn-mus,
 
Health effects :
Human poison by an unspecified route. 
Experimental poison by
ingestion, intravenous, subcutaneous and intraperitoneal
routes. 
An experimental tumorigen. 
Experimental reproductive
effects. 
Human mutagenic data. 
A severe eye irritant. 
A
powerful caustic and irritant to skin, eyes and mucous
membranes. 
Swallowing can cause severe gastroenteritis that may
be fatal.
 
Effects on anthropods :
Tanytarsus dissimilis, LC50, 2 d, 0.420 mg/l (Holcombe et al.
1987).
 
Effects on microorganisms :
Toxicity threshold (cell multiplication inhibition test):
bacteria (Pseudomonas putida): 0.006 mg/l
(Bringmann & Kühn 1980a)
 
EC50 values to algae, mg/l :
0.17  96hr, Skeletonema costatum, pht,
  USEPA 1980
 
LOEC values to algae, mg/l :
0.05  Scenedesmus, Bringmann & Kühn 1959
 
LC50 values to crustaceans, mg/l :
0.042  1d, Daphnia magna
0.015  2d, Daphnia magna
  Khangarot et al. 1987
  --
0.56  4d, Orconectes immunis
  Holcombe et al. 1987
 
EC50 values to crustaceans, mg/l :
0.006  2d, mbt, Crangonyx pseudogracilis
0.005  4d, mbt, Crangonyx pseudogracilis
  Martin & Holdich 1986
  --
0.023  1d, mbt, Daphnia magna
0.01  2d, mbt, Daphnia magna
  Khangarot & Ray 1987
  --
0.0009  2d, mbt, Daphnia magna
  Holcombe et al. 1987
 
LC50 values to fishes, mg/l :
0.029  96hr, Salmo gairdneri, Hale 1977
  --
0.0067  96hr, flow-through, Pimephales promelas
0.014  96hr, static, Pimephales promelas
0.0173  96hr, flow-through, Ictalurus punctatus
  Holcombe et al. 1983
  --
0.06  96hr, Lepomis macrochirus
  Buccafusco et al. 1981
  --
0.013  4d, Lepomis macrochirus
0.009  4d, Pimephales promelas
0.006  4d, Salmo gairdneri
  Holcombe et al. 1987
 
LOEC values to fishes, mg/l :
0.0001  Salmo gairdneri, Nebeker et al. 1983
 
Other information of water organisms :
Aplexa hypnorum, LC50, 4 d, 0.083 mg/l (Holcombe et al. 1987). 
LC50, 0.241 mg/l, 96hr, renewal, Aplexa hypnorum
(Holcombe et al. 1983)

Toxicity threshold (cell multiplication inhibition test):
green algae (Scenedesmus quadricauda): 0.0095 mg/l
protozoa (Entosiphon sulcatum): 0.58 mg/l
(Bringmann & Kühn 1980a)

Chlorella vulgaris, effects on growth , 0.03 mg/l (Stokes 1973). 
Chlorella fusca, EC100, 0.1 mg/l (Stokes 1973).

Gastropoda, LC50, 96 hr, 0.241 mg/l (Holcombe et al. 1983).

Crassostrea virginica, larvae, LC50, 48 hr, 0.0046 - 0.0064
mg/l (Calabrese et al. 1973),

Salmo gairdneri, eggs, juv., LC100, 0,0013 mg/l (Nebeker et al.
1983).

Salvelinus fontinalis, MATC, 0.00009 - 0.00017 mg/l (Davies
1975).

References
2285Anon. 1989. Miljöfarliga ämnen - exempellista och vetenskaplig dokumentation. 303 p. Stockholm. Rapport från kemikalieinspektionen (KEMI) 10.
188Bringmann, G. & Kühn, R. 1980a. Comparison of the toxicity thresholds of water pollutants to bacteria, algae and protozoa in the cell multiplication inhibition test. Water Res. 14: 231 - 241.
2900Bringmann, G. & Kühn, R. 1959. Wasser-toxikologische Untersuchungen mit Protozoen als Testorganismen. GesundheitsIngenieur 8: 239 - 242.
2902Calabrese, A., Collier, R.S., Nelson, D.A. & MacInnes, J.R. 1973. The toxicity of heavy metals to embryos of the American oyster. Marine Biology 18: 162 - 166.
2548Christensen, H.E. (Ed.) 1973. The toxic substances list, 1973 edition. U.S. Department of Health, Education and Welfare, Rockville, Maryland, June 1973.
2903Davies, P.H. 1975. The need to establish heavy metal standards on the basis of dissolved metals, Chapter 5. In: Andrew, R.W., Hodson, P.V. & Konasewich, D.E. (Eds.) 1976. Toxicity to biota of metal forms in natural waters, Duluth Minn., Oct. 1975, Great Lakes Research Advisory Board.
522Hale, J.G. 1977. Toxicity of metal mining wastes. Bull. Environ. Contam. Toxicol. 17: 66.
1891Holcombe, G.W. et al. 1987. Simultaneous multiple species testing: acute toxicity of 13 chemicals to 12 diverse freshwater amphibian, fish, and invertebrate families. Arch. Environ. Contam. Toxicol. 16: 697.
594Holcombe, G.W., Phipps, G.L. & Fiandt, J.T. 1983. Toxicity of selected priority pollutants to various aquatic organisms. Ecotoxicol. Environ. Saf. 8(2): 106 - 117.
1810Khangarot, B.S. & Ray, P.K. 1987a. Correlation between heavy metal acute toxicity values in Daphnia magna and fish. Bull. Environ. Contam. Toxicol. 38: 722 - 726.
1949Khangarot, B.S. et al. 1987a. Daphnia magna as a model to assess heavy metal toxicity: comparative assessment with mouse system. Acta hydrochim. Hydrobiol. 15: 427.
1589Lewis, R.J. & Sweet, D.V. 1984. Registry of toxic effects of chemical substances. National Institute for Occupational Safety and Health. No. 83-107-4.
1763Martin, T.R. & Holdich, D.M. 1986. The acute lethal toxicity of heavy metals to peracarid crustaceans (with particular reference to fresh-water asellids and gammarids). Water Res. 20(9): 1137 - 1147.
1017Nebeker, A.V., McAuliffe, C.K., Mshar, R. & Stevens, D.G. 1983. Toxicity of silver to steelhead and rainbow trout, fathead minnows and Daphnia magna. Environ. Toxicol. Chem. 2: 95 - 104.
2522Sax, N.I. & Lewis, R.J.Sr. 1987. Hawley's condensed chemical dictionary. Eleventh edition. Van Nostrand Reinhold Company. New York. pp. 1288.
2723Sax, N.I. & Lewis, Sr., R.J. 1989. Dangerous properties of industrial materials. Seventh edition. Van Nostrand Reinhold. New York.
2901Stokes, P.M. 1973. Heavy metal tolerance in algae isolated from polluted lakes near Sudbury, Ontario smelters. Water Poll. Res. Can. 8: 178.
2899USEPA 1980. Ambient Water Quality Criteria for Silver. USEPA Report, NTIS No. PB 81-117822, USEPA Office of Water, Washington, D.C.

 
 
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