| Chemical |
Allylchloride |
| CAS-number : |
107-05-1 |
| |
| Synonyms : |
| 3-chloro-1-propene |
| 3-chloro-1-propylene |
| 3-chloropropene |
| allyylikloridi |
| chloroallylene |
| |
| Sumformula of the chemical : |
| CH2=CH-CH2Cl
C3H5Cl |
| EINECS-number : |
| 2034576 |
| |
| State and appearance : |
Colourless to pale yellow.
|
| |
| Odor : |
Characteristic: garlic-onion pungency, green.
Threshold Odour Concentration; 0.660 mg/m3 = 0.21 ppm
1500 ppm
50 % recognition: 0.21 ppm
100 % recognition: 25 ppm
Population Identification Threshold 50: 0.21 ppm
Population Identification Threshold 100: 0.47 ppm
1.5 mg/m3 = 0.47 ppm
(Verschueren 1983).
|
| |
| Molecular weight : |
76.53 |
| |
| Spesicif gravity (water=1) : |
| 0.94 |
at 20/4 °C |
| |
| Vapor density (air=1) : |
| 2.64 |
|
| |
| Conversion factor, 1 ppm in air=_mg/m3 : |
| 3.18 |
mg/m3 |
| |
| Conversion factor, 1 mg/m3 in air=_ppm : |
| 0.314 |
ppm |
| |
| Vapor pressure, mmHg : |
| 340 |
20°C |
| 440 |
30°C |
| |
| Water solubility, mg/l : |
| 100 |
|
| 2300 |
MITI 1992 |
| |
| Melting point, °C : |
| -135 |
|
| -134.5 |
MITI 1992 |
| |
| Boiling point, °C : |
| 44 |
44 - 45.5 |
| 45.5 |
|
| 45 |
MITI 1992 |
| |
| Henry's law constant, Pa x m3/mol : |
| 919.2 |
calc. Yaws et al. 1991 |
| |
| Photochemical degradation in air : |
Photooxidation half-life in air:
28.8hr - 3.03hr, scientific judgement based upon measured rate
constant for reaction with hydroxyl radicals and estimated rate
constant for reaction with ozone (Howard 1991).
|
| |
| Hydrolysis in water : |
First-order hydrolysis half-life:
14d - 6.9d, (t1/2 at pH 5-9) based upon measured neutral
hydrolysis rate constants at 20 °C (low t1/2) and 25 °C (high
t1/2) (Howard 1991).
|
| |
| Chemical oxygen demand, g O2/g : |
| 0.86 |
5 days, Bridie et al. 1979 |
| |
| Biochemical oxygen demand, g O2/g : |
| 0.23 |
5 days, Bridie et al. 1979 |
| |
| Half-life in air, days : |
| 1.2 |
28.8hr - 3.03hr, |
| 0.126 |
scientific judgement based upon estimated photooxidation half-life in air. |
| |
Howard 1991 |
| |
| Half-life in soil, days : |
| 14 |
14d - 6.9d, |
| 6.9 |
(t1/2 at pH 5-9) based upon measured neutral hydrolysis rate constants in water at 20 °C (low t1/2) and 25 °C (high t1/2). |
| |
Howard 1991 |
| |
| Half-life in water, days : |
| 14 |
14d - 6.9d, |
| 6.9 |
in surface half-life and in ground water: (t1/2 at pH 5-9) based upon measured neutral hydrolysis rate constants at 20 °C (low t1/2) and 25 °C (high t1/2). |
| |
Howard 1991 |
| |
| Aerobic degradation in water : |
Aerobic half-life:
4we - 7d, scientific judgement based upon unacclimated aqueous
aerobic sceering test data (Howard 1991).
|
| |
| Anaerobic degradation in water : |
Anaerobic half-life:
16we - 28d, scientific judgement based upon estimated
unacclimated aqueous aqerobic biodegradation half-life.
(Howard 1991).
|
| |
| Total degradation in water : |
Biodegradation:
55-69% by BOD
period: 28d
substance: 100 mg/l
sludge: 30 mg/l
(MITI 1992)
|
| |
| Ready biodegradability : |
Confirmed to be biodegradable (Anon. 1987). |
| |
| Other information of degradation : |
Impact on biodegradation processes: 75 % decrease of
nitrification by activated sludge at 180 mg/l (Meinck et al.
1970).
|
| |
| Bioconcentration factor, fishes : |
| 0.14 |
< 0.14 - 0.88, 6w, Cyprinus carpio, conc 0.5 mg/l, |
| 0.88 |
|
| 1.3 |
< 1.3 - 5.60, 6w, Cyprinus carpio, conc 0.05 mg/l, |
| 5.6 |
MITI 1992 |
| |
| LD50 values to mammals in oral exposure, mg/kg : |
| 64 |
orl-rat, Lewis & Sweet 1984 |
| |
-- |
| 700 |
orl-rat, Patty 1967 |
| |
| LD50 values to mammals in non-oral exposure , mg/kg : |
| 2066 |
kn-rbt, Lewis & Sweet 1984 |
| |
| Other information of mammals : |
Rat: max, exposure time concentrations: 290 ppm, 3 hr
inhalation: 2900 ppm, 1 hr
29300 ppm, 15 min
Rat, guinea pig, rabbit: liver injury: 8 ppm, 7 hr/day, 5
days/w, 28 days
Rat, guinea pig, rabbit: died after 127 - 134 exposures at 3 ppm
(Patty 1967).
|
| |
| Health effects : |
Man: very irritating to the eyes and upper respiratory tract
eye irritating 50 - 100 ppm
(Patty 1967)
|
| |
| Carcinogenicity : |
NCI carcinogenesis bioassay completed: results indefinite,mus;
negative,rat (Lewis & Sweet 1984).
|
| |
| Effects on microorganisms : |
Toxicity threshold (cell multiplication inhibition test):
bacteria (Pseudomonas putida): 115 mg/l (Bringmann & Kühn
1980a).
|
| |
| LOEC values to algae, mg/l : |
| 6.3 |
Scenedesmus quadricauda, |
| |
Bringmann & Kuhn 1980 a |
| |
| LC50 values to fishes, mg/l : |
| 19.8 |
srv, act, 96 hr, Pimephales promelas, |
| |
Pickering & Henderson 1966 |
| 10 |
srv, act, 24 hr, Carassius auratus, |
| |
Bridie et al. 1979 |
| 1.2 |
srv, schr, 14 d, Poelicia reticulata, |
| |
Hermens et al. 1985 |
| |
-- |
| 6.9 |
48hr, Oryzias latipes, MITI 1992 |
| |
| Other information of water organisms : |
Toxicity threshold (cell multiplication inhibition test):
green algae (Scenedesmus quadricauda: 6.3 mg/l
protozoa (Entosiphon sulcatum): 8.4 mg/l
protozoa (Uronema parduczi): > 240 mg/l
(Bringmann & Kühn 1980a, 1980b).
|
| |
| Other information : |
Hardness of water decreases toxicity (Pickering & Henderson
1966).
|
References |
| 1848 | Anon. 1987a.
The list of the existing chemical substances tested
on biodegradability by microorganisms or bioaccumulation in
fish body by Chemicals Inspection & Testing Institute.
Ministry
of International Trade and Industry, MITI.
Japan. |
| 1680 | Bridie, A.L., Wolff, C.J.M. & Winter, M. 1979.
BOD and COD of
some petrochemicals.
Water Res. 13: 627 - 630. |
| 188 | Bringmann, G. & Kühn, R. 1980a.
Comparison of the toxicity
thresholds of water pollutants to bacteria, algae and
protozoa in the cell multiplication inhibition test.
Water
Res. 14: 231 - 241. |
| 189 | Bringmann, G. & Kühn, R. 1980b.
Bestimmung der biologischen
Schadwirkung wassergefahrdender Stoffe gegen Protozoen.
II.
Bakterienfressende Ciliaten, Z.
Wasser/Abwasser Forsch. 1: 26 -
31. |
| 577 | Hermens, J., Leeuwangh, P. & Musch, A. 1985a.
Joint toxicity of
mixtures of groups of organic aquatic pollutants to the
guppy (Poecilia reticulata).
Ecotox.
Environm.
Safety 9: 321 -
326. |
| 3120 | Howard, P.H., Boethling, R.S., Jarvis, W.F., Meylan, W.M. &
Michalenko, E.M., Handbook of Environmental Degradation Rates,
1991.
Lewis Publicers, Inc., Chelsea, Michigan, U.S.A.,
pp. 725.
|
| 1589 | Lewis, R.J. & Sweet, D.V. 1984.
Registry of toxic effects of
chemical substances.
National Institute for Occupational Safety
and Health.
No. 83-107-4. |
| 950 | Meinck, F., Stoof, H. & Kohlschutter, H. 1970.
Les eaux
residuaires industrielles. |
| 3105 | MITI 1992.
Biodegradation and bioaccumulation data of existing
chemicals based on the CSCL Japan.
Compild under the Safety
Division Basic Industries Bureau Ministry of International
Trade & Industry, Japan.
Edited by Chemicals Inspection &
Testing Institute, Japan.
|
| 1644 | Patty, F.A. 1967.
Industrial hygiene and toxicology.
Vol 2.
Interscience Publishers. |
| 1129 | Pickering, Q.H. & Henderson, C. 1966.
Acute toxicity of some
important petrochemicals to fish.
J.
Water Pollut.
Control
Feder. 38: 1419 - 1429. |
| 3030 | Yaws, C., Yang, H-C. & Pan, X. 1991.
Henry's law constants for
362 organic compounds in water.
Chemical Engineering.
November.
p 179 - 185. |
