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Data bank of environmental chemicals     |     The Finnish Environment Institute (SYKE)
 


26.4.2024

Data bank of environmental properties of chemicals


Chemical
Hydrogen cyanide
CAS-number :
74-90-8
 
Synonyms :
HCN
hydrocyanic acid
vetysyanidi
 
Sumformula of the chemical :
CHN
EINECS-number :
2008216
 
State and appearance :
colourless gas or liquid
 
Molecular weight :
27.03
 
Vapor pressure, mmHg :
620  20°C
 
Melting point, °C :
-13.3 
 
Boiling point, °C :
25.6 
 
Photochemical degradation in air :
Photooxidation half-life in air:
89.1d - 2.4yr,
scientific judgement based upon measured rate data for the
vapor phase reaction with hydroxyl radicals in air
(Howard 1991).
 
Half-life in air, days :
89.1  89.1d - 2.4yr,
876  based upon photooxidation half-life in air,
  Howard 1991
 
Half-life in soil, days :
28  4w - 6mo,
180  scientific judgement based upon estimated aqueous
  aerobic biodegradation half-life,
  Howard 1991
 
Half-life in water, days :
28  4w - 6mo,
180  in surface water, scientific judgement based upon
  estimated aqueous aerobic biodegradation half-life,
56  8w - 12mo,
360  in ground water, scientific judgement based upon
  estimated aqueous aerobic biodegradation half-life,
  Howard 1991
 
Aerobic degradation in water :
Aerobic half-life:
4w - 6mo,
scientific judgement based upon acclimated aerobic screening 
test data (Howard 1991).
 
Anaerobic degradation in water :
Anaerobic half-life:
16w - 24mo,
scientific judgement based upon estimated aqueous aerobic 
biodegradation half-life (Howard 1991).
 
LD50 values to mammals in oral exposure, mg/kg :
3.7  orl-mus, Lewis & Sweet 1984
 
LDLo values to mammals in oral exposure, mg/kg :
0.57  orl-hmn, Lewis & Sweet 1984
orl-pig, - " -
 
LCLo values to mammals in inhalation exposure, mg/kg :
120  1 hr, ihl-hmn, Lewis & Sweet 1984
 
LCLo values to mammals in inhalation exposure, ppm :
323  5 min, ihl-mus, Lewis & Sweet 1984
 
LC50 values to crustaceans, mg/l :
0.17  96 hr, Gammarus pseudolimnaeous,
  Verschueren 1983
 
LC50 values to fishes, mg/l :
0.125  96hr, Pimephales promelas
0.057  96 hr, Salmo gairdneri, Broderius &
  Smith 1979

References
191Broderius, S.J. & Smith, L.L. 1979. Lethal and sublethal effects of binary mixtures of cyanide and hexavalent chromium, zinc, or ammonia to the fathead minnow (Pimephales promelas) and rainbow trout (Salmo gairdneri). J. Fish. Res. Bd. Can. 36: 164.
3120Howard, P.H., Boethling, R.S., Jarvis, W.F., Meylan, W.M. & Michalenko, E.M., Handbook of Environmental Degradation Rates, 1991. Lewis Publicers, Inc., Chelsea, Michigan, U.S.A., pp. 725.
1589Lewis, R.J. & Sweet, D.V. 1984. Registry of toxic effects of chemical substances. National Institute for Occupational Safety and Health. No. 83-107-4.
1468Verschueren, K. 1983. Handbook of environmental data of organic chemicals. Van Nostrand Reinhold Co. Inc., New York. 1310 s.

 
 
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