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Data bank of environmental chemicals     |     The Finnish Environment Institute (SYKE)
 


27.4.2024

Data bank of environmental properties of chemicals


Chemical
Zinc carbonate
CAS-number :
3486-35-9
 
Synonyms :
Carbonic acid, zinc salt
Carbonic acid, zinc salt (1:1)
sinkkikarbonaatti.
 
Sumformula of the chemical :
CH2O3.Zn
EINECS-number :
2224776
 
Uses :
As pigment in manufacture of porcelains, pottery, rubber,
astringent; tropical antiseptic; cosmetics; and lotions.
 
State and appearance :
White crystalline powder. 
Will sink.
 
Molecular weight :
125.39
 
Spesicif gravity (water=1) :
4.42 
 
Other physicochemical properties :
Nonflammable.

Will emit carbon dioxide and zinc oxide in fires.

Evolves carbon dioxide at 300 °C.

Practically insoluble in water, 10 ppm at 15 °C.
 
Other information of degradation :
Persistent (Sax 1986).
 
Other information of bioaccumulation :
Food chain contamination potential moderate. 
Zinc will
accumulate in some organisms, but is not considered to be
bioconcentrative (Sax 1986).
 
Health effects :
When heated, evolves zinc oxide fumes which can cause a disease
known as brass founders ague or brass chills. 
Ingestion of zinc
salts leads to an emetic reaction (Sax 1986).

Eye, skin, respiratory, and mucous membrane irritant (Sax 1986).

Skin contamination may produce irritation, rash, and reddening. 
Contamination of mucous membranes produces reddening and
irritation. 
Exposure of eye may produce pain, photophobia and
corneal damage. 
Inhalation may produce coughing and choking
(Sax 1986).

Zinc salts are astringent, corrosive to the skin, irritating to
the gastrointestinal tract, and may act as emetics, where the
emetic concentration in water may be between 675 and 2280 ppm. 
After large doses have been ingested, fatal collapse may occur as
a result of serious damage to the buccal and gastroenteric
mucous membranes. 
The zinc ion is too poorly absorbed to induce
acute systemic intoxication. -  
When in fires or highly heated,
zinc oxides are emitted which may act as a skin irritant and
when inhaled give symptoms af metal-fume fever (Sax 1986).

Chronic hazard level: Generally, zinc compounds have no
cumulative effects. 
The continued administration of zinc salts
in small doses has no effect in man except those of disordered
digestion and constipation (Sax 1986).
 
Effects on wastewater treatment :
Little effect on water treatment process since a level af 10
mg/l is required for an effect (Sax 1986).
 
LC50 values to fishes, mg/l :
63  as zinc, 96hr, Pimephales promelas
  Sax 1986
 
Other information of water organisms :
Salmo gairdneri, 0.0793 mg/g, 280 d, change in length and/or
weight (Satoh et al. 1987b).
 
Other information :
Taste threshold, lower: 6 ppm; medium: 27.2 ppm (Sax 1986).

References
1973Pilli.A., Carle, D.O., Kline. E., Pickering. Q. & Lazorchak. J. 1988. Effets of pollution on freshwater organisms. JWPCF 60(6): 994 - 1065.
2078Satoh, S. et al. 1987b. Availability to rainbow trout of zinc in white fish meal and of various zinc compounds. Nippon Suisan Gakkaishi (Bull. Jpn. Soc. Sci. Fish.) 53: 595.
2147Sax, I. 1986. Hazardous chemicals information annual No. 1. Van Nostrand Reinhold Information Services, New York. 766 s.

 
 
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