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Data bank of environmental chemicals     |     The Finnish Environment Institute (SYKE)
 


20.4.2024

Data bank of environmental properties of chemicals


Chemical
n-butane
CAS-number :
106-97-8
 
Sumformula of the chemical :
C4H10
EINECS-number :
2034487
 
State and appearance :
Colourless gas.
 
Odor :
Threshold odour concentration:
12100 mg/m3 = 4960 ppm
not detectable: < 5000 ppm (Patty 1967)
recognition: 6160 mg/m3 (Verschueren 1983)
3000 mg/m3 (Laffort & Dravnieks 1973)
5.5 ppm (Verschueren 1983).
 
Molecular weight :
58.14
 
Spesicif gravity (water=1) :
0.6  liquified
 
Vapor density (air=1) :
2.01 
 
Conversion factor, 1 ppm in air=_mg/m3 :
2.42  mg/m3
 
Conversion factor, 1 mg/m3 in air=_ppm :
0.41  ppm
 
Vapor pressure, mmHg :
1823  at 25 °C
 
Water solubility, mg/l :
61  at 20 °C
30  at 15 °C
21  at 38 °C
 
Melting point, °C :
-135  -135/-138 °C
-138 
 
Boiling point, °C :
-1 
 
Photochemical degradation in air :
Estimated lifetime under photochemical smog conditions in S.E. 
England: 15 hr (Verschueren 1983, Stuhl 1973).
 
Total degradation in water :
Incubation with natural flora in the groundwater - in presence of
the other components of high-octane gasoline (0.100 ml/l):
biodegradation: 0 % after 192 hr at 13 °C (initial conc.
0.00063 ml/l (Jamison et al. 1976).
 
Health effects :
Man: drowsiness, no other effects; 10000 ppm, 10 min (Patty
1967).

References
1809Altshuller, A.P. & Bufalini, J.J. 1971. Photochemical aspects of air pollution; A Review. Environm. Sci. & Techn. 5(1).
1873Jamison. V.W., Raymond, R.L. & Hudson, J.O. 1976. Biodegradation of high-octane gasoline. In: J.M. Sharpley and A.M. Kaplan (eds.). Proceedings of the Third International Biodegradation Symposium. Applied Science Publishers, pp. 187 - 196.
1871Laffort, P. & Dravnieks, A. 1973. An approach to a physico-chemical model of olfactory stimulation in vertebrates by single compounds. J. Theor. Biol. 38: 335 - 345.
1644Patty, F.A. 1967. Industrial hygiene and toxicology. Vol 2. Interscience Publishers.
1872Stuhl. F. 1973. Rate constant for the reaction of OH with n-C4H10. Z. Naturforsch 28a: 1383 - 1384.
1468Verschueren, K. 1983. Handbook of environmental data of organic chemicals. Van Nostrand Reinhold Co. Inc., New York. 1310 s.

 
 
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