| Chemical |
Phoxim |
| CAS-number : |
14816-18-3 |
| |
| Synonyms : |
| 2-(diethoxyphosphinothionyloxyimino)2-phenylacetonitrile |
| alpha-(((diethoxyphosphinothioyl)oxy)imino)-benzeneacetonitrile |
| Baition |
| diethoxyphosphinothioyloxyimino(phenyl)acetonitrile |
| Foksiimi |
| O,O-Diethyl-alpha-cyanobenzylideneamino-oxyphosphonothioate |
| OMS-1170 |
| phenylglyoxylonitrile oxime O,O-diethyl phosphorothionate |
| SRA 7502 |
| Volation |
| |
| Sumformula of the chemical : |
| C12H15N2O3PS |
| |
| Purity, % : |
| 80 |
at least 80%, WPSREG 1993 |
| |
| Known impurities : |
* in technical grade
O,O-Diethyl phosphorochloridotioate (CAS 2524-04-1) < 0.5 %;
O,O,O-Triethyl phosphorothioate (CAS 126-68-1) < 0.6 - 1.2 %;
Oximether (=alpha-(ethoxyimino)benzeneacetonitrile < 1.0 - 1.5 %;
Cyanooxime (=alpha-(hydroxyimino)benzeneacetonitrile < 1.5 %;
4- Ethoxy-7-phenyl-3,5-dioxa-6-aza-4-phospha-6-octen-8-amide-
4- sulfide < 0.3 - 1.0 %;
E-Volaton (=E-alpha-(((diethoxyphosphinothionyl)oxy)imino)benzene-
acetonitrile < 3.0 - 4.5 %;
5-Ethoxy-2,8-diphenyl-4,6-dioxa-3,7-diaza-5-phospha-2,7-nonadiene-
dinitrile 5-sulfide < 0.5 - 1.0 %;
Benzylcyanide (=benzeneacetonitrile) (CAS 140-29-4) < 2.5 %;
Ammoniumchloride or ammoniumsulfate < 1.0 %;
Water < 0.2 %;
n-Butanol (solvent) 9.0 - 12 %
(WSPREG 1993) |
| |
| Uses : |
Active ingredient in insecticides.
Active ingredient in liquid wood preservatives with preventive
efficancy against wood-destroying fungi including softrot and
wood-destroying insects (WPSREG 1993).
|
| |
| State and appearance : |
Liquid (WSPREG 1993).
|
| |
| Density, kg/m3 : |
| 0.0012 |
20°C |
| 0.0011 |
technical grade |
| |
WPSREG 1993 |
| |
| Vapor pressure, mmHg : |
| 0.000015 |
calculated, 20°C |
| 2.625 |
technical grade, 20°C |
| |
WPSREG 1993 |
| |
| Water solubility, mg/l : |
| 10 |
< 10, MITI 1992 |
| |
-- |
| 7 |
20°C |
| 1.5 |
20°C |
| |
technical grade not soluble in water |
| |
WPSREG. 1993 |
| |
| Flashing point, °C : |
| 38 |
WPSREG 1993 |
| |
| Log octanol/water coefficient, log Pow : |
| 4.38 |
MITI 1992 |
| 4.38 |
WPSREG 1993 |
| |
| Mobility : |
Rf = 0.12 +/- 0.04 (thin-layer plate) (WPSREG 1993).
|
| |
| Other physicochemical properties : |
Solubility in dichlormethane > 500 g/kg, in cyclohexane,
2-propanol, toluene and methylen chlorid > 600 g/kg (WPSREG
1993).
|
| |
| Total degradation in soil : |
T 1/2 = 25d, 40d (20-22°C) or 11-18 d (10-15°C) (WPSREG 1993).
|
| |
| Total degradation in water : |
Biodegradation:
3-8% by BOD
period: 28d
substance: 100 mg/l
sludge: 30 mg/l
(MITI 1992)
|
| |
| Bioconcentration factor, fishes : |
| 781 |
781 - 1610, 8w, Cyprinus carpio, conc 0.0166 mg/l, |
| 1610 |
|
| 412 |
412 - 1020, 8w, Cyprinus carpio, conc 0.00166 mg/l, |
| 1020 |
MITI 1992 |
| |
-- |
| 412 |
412 - 1610, Cyprinus carpio |
| 1610 |
WPSREG 1993 |
| |
| LD50 values to mammals in oral exposure, mg/kg : |
| 250 |
250 - 2340, orl-mam, |
| 2340 |
WPSREG 1993 |
| |
| LD50 values to birds in oral exposure, mg/kg : |
| 10 |
orl-Agelaius phoeniceus |
| 23.7 |
orl-Sturnus vulgaris |
| 23.7 |
orl-Coturnix coturnix |
| 5.62 |
orl-Passer domesticus |
| 75 |
orl-Quiscalus quiscula |
| 23.7 |
orl-Columba livia |
| |
Schafer et al. 1983 |
| |
-- |
| 5.6 |
5.6 - 75, orl-birds, |
| 75 |
WPSREG 1993 |
| |
| EC50 values to algae, mg/l : |
| 0.62 |
24h, Scenedesmus subspicatus, WPSREG 1993 |
| |
| NOEC values to algae, mg/l : |
| 0.1 |
< 0.1, Scenedesmus subspicatus, |
| |
(nominal consentrations), WPSREG 1993 |
| |
| EC50 values to crustaceans, mg/l : |
| 0.00052 |
48hr, Penaeus duodarum |
| 0.00068 |
48hr, Daphnia magna |
| |
WPSREG 1993 |
| |
| LOEC values to crustaceans, mg/l : |
| 0.00008 |
21d, Daphnia magna, WPSREG 1993 |
| |
| NOEC values to crustaceans, mg/l : |
| 0.000068 |
< 0.000068, 48h, Daphnia magna |
| 0.000042 |
21d, Daphnia magna |
| 0.0001 |
48h, Penaeus duodarum |
| |
WPSREG 1993 |
| |
| LC50 values to fishes, mg/l : |
| 0.1 |
0.1 - 1.0, srv,act, Salmo gairdneri, |
| 1 |
Pesticide Manual 1983 |
| 0.1 |
0.1 - 1.0, srv,act, Cyprinus carpio, |
| 1 |
Pesticide Manual 1983 |
| 1 |
1 - 10, srv,act, Carassius auratus, |
| 10 |
Pesticide Manual 1983 |
| |
-- |
| 3.16 |
48hr, Oryzias latipes, MITI 1992 |
| |
-- |
| 0.22 |
96h, Lepomis macrochirus |
| 0.00028 |
48h, Leiostomus xanthurus |
| 2.14 |
96h, Leuciscus idus melanotus, |
| |
WPSREG 1993 |
| |
-- |
| 0.082 |
96hr, Lepomis macrochirus, AQUIRE 1994 |
| |
| NOEC values to fishes, mg/l : |
| 0.36 |
0.36 - 0.50, 96h, Salmo gairdneri, |
| 0.5 |
|
| 0.000001 |
< 0.000001, 48h, Leiostomus xanthurus, |
| 1 |
96h, Leuciscus idus melanotus, |
| 0.14 |
96h, Lepomis macrochirus, |
| |
WPSREG 1993 |
References |
| 70 | Anon. 1983c.
Pesticide Manual.
Worthing, C.R.
(toim.)
A world compedium.
The British Crop Biotection Council.
London. 7 th edition. |
| 3107 | AQUIRE 1993 -.
Aquatic Toxity Information Retrieval Database.
U.S.Environmental Protection Agency, Office of Pesticides and
Toxic Substances, Washington, D.C.
|
| 3105 | MITI 1992.
Biodegradation and bioaccumulation data of existing
chemicals based on the CSCL Japan.
Compild under the Safety
Division Basic Industries Bureau Ministry of International
Trade & Industry, Japan.
Edited by Chemicals Inspection &
Testing Institute, Japan.
|
| 1743 | Schafer , E.W.Jr., Bowles, W.A.Jr., Hurlbut, J. 1983.
The acute
oral toxicity, repellency and hazard potential of 993 chemicals to
one or more species of wild and domestic birds.
Arch.
Environ.
Contam.
Toxicol. 12: 355 - 382. |
| 3119 | WPSREG.
Application for registration of wood preservatives/
slimicides.
National Board of Waters and the Environment,
Chemicals Control Unit.
|
