Chemical |
Chloroethane |
CAS-number : |
75-00-3 |
|
Synonyms : |
etyylikloridi |
Kloorietaani |
|
Sumformula of the chemical : |
C2H5Cl |
EINECS-number : |
2008305 |
|
Uses : |
Solvent.
|
|
Water solubility, mg/l : |
4470 |
20 °C |
7400 |
MITI 1992 |
|
Melting point, °C : |
-142.5 |
MITI 1992 |
|
Boiling point, °C : |
12.3 |
|
12.5 |
MITI 1992 |
|
Log octanol/water coefficient, log Pow : |
1.43 |
Sangster 1989 |
1.39 |
MITI 1992 |
|
Henry's law constant, Pa x m3/mol : |
701.1 |
calc. Yaws et al. 1991 |
|
Photochemical degradation in air : |
Photooxidation half-life in air:
6.67d - 66.8d,
based upon measured rate constants for reaction with hydroxyl
radical in air (Howard 1991).
|
|
Hydrolysis in water : |
First-order hydrolysis half-life:
912 hours (38 days) at 25°C,
based upon neutral hydrolysis rate constant which was
extrapolated from data at higher temperatures (Howard 1991).
|
|
Half-life in air, days : |
6.67 |
6.67d - 66.8d, |
66.8 |
based upon photooxidation half-life in air, |
|
Howard 1991 |
|
Half-life in soil, days : |
7 |
7d - 4w, |
28 |
scientific judgement based upon estimated |
|
unacclimated aerobic aqueous biodegradation |
|
half-life, |
|
Howard 1991 |
|
Half-life in water, days : |
7 |
7d - 4w, |
28 |
in surface water, scientific judgement based upon |
|
estimated unacclimated aerobic aqueous |
|
biodegradation half-life, |
14 |
14d - 8w, |
56 |
in ground water, scientific judgement based upon |
|
estimated unacclimated aerobic aqueous |
|
biodegradation half-life, |
|
Howard 1991 |
|
Aerobic degradation in water : |
Aerobic half-life:
7d - 4w,
scientific judgement based upon aqueous aerobic screening test
data for 1-chloropropane and 1-chlorobutane (Howard 1991).
|
|
Anaerobic degradation in water : |
Anaerobic half-life:
28d - 16w,
scientific judgement based upon estimated unacclimated aerobic
aqueous biodegradation half-life (Howard 1991).
|
|
Total degradation in water : |
Biodegradation:
1% by BOD 1% by BOD
period: 28d period: 28d
substance: 1.84 mg/l substance: 4.19 mg/l
sludge 2 mg/l sludge: 2 mg/l
(MITI 1992)
|
|
LC50 values to fishes, mg/l : |
40 |
srv,act, 96 hr, Pimephales promelas, |
|
Phipps & Holcombe 1985 |
19 |
srv,act, 96 hr, Carassius auratus, |
|
Phipps & Holcombe 1985 |
36 |
srv,act, 96 hr, Salmo gairdneri, |
|
Phipps & Holcombe 1985 |
References |
3120 | Howard, P.H., Boethling, R.S., Jarvis, W.F., Meylan, W.M. &
Michalenko, E.M., Handbook of Environmental Degradation Rates,
1991.
Lewis Publicers, Inc., Chelsea, Michigan, U.S.A.,
pp. 725.
|
3105 | MITI 1992.
Biodegradation and bioaccumulation data of existing
chemicals based on the CSCL Japan.
Compild under the Safety
Division Basic Industries Bureau Ministry of International
Trade & Industry, Japan.
Edited by Chemicals Inspection &
Testing Institute, Japan.
|
1123 | Phipps, G.L. & Holcombe, G.W. 1985.
A method for multiple
species toxicant testing: acute toxicity of 10 chemicals to
5 vertebrates and 2 invertebrates.
Environm.
Pollut.
(Ser A)
38: 141 - 157. |
3104 | Sangster, J. 1989.
Octanol-water partition coefficients of
simple organic compounds.
J.
Phys.
Chem.
Ref.
Data, Vol 18, No.
3: 1111 - 1229. |
3030 | Yaws, C., Yang, H-C. & Pan, X. 1991.
Henry's law constants for
362 organic compounds in water.
Chemical Engineering.
November.
p 179 - 185. |