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Data bank of environmental chemicals     |     The Finnish Environment Institute (SYKE)
 


26.4.2024

Data bank of environmental properties of chemicals


Chemical
Chloroethane
CAS-number :
75-00-3
 
Synonyms :
etyylikloridi
Kloorietaani
 
Sumformula of the chemical :
C2H5Cl
EINECS-number :
2008305
 
Uses :
Solvent.
 
Water solubility, mg/l :
4470  20 °C
7400  MITI 1992
 
Melting point, °C :
-142.5  MITI 1992
 
Boiling point, °C :
12.3 
12.5  MITI 1992
 
Log octanol/water coefficient, log Pow :
1.43  Sangster 1989
1.39  MITI 1992
 
Henry's law constant, Pa x m3/mol :
701.1  calc. Yaws et al. 1991
 
Photochemical degradation in air :
Photooxidation half-life in air:
6.67d - 66.8d,
based upon measured rate constants for reaction with hydroxyl
radical in air (Howard 1991).
 
Hydrolysis in water :
First-order hydrolysis half-life:
912 hours (38 days) at 25°C,
based upon neutral hydrolysis rate constant which was
extrapolated from data at higher temperatures (Howard 1991).
 
Half-life in air, days :
6.67  6.67d - 66.8d,
66.8  based upon photooxidation half-life in air,
  Howard 1991
 
Half-life in soil, days :
7d - 4w,
28  scientific judgement based upon estimated
  unacclimated aerobic aqueous biodegradation
  half-life,
  Howard 1991
 
Half-life in water, days :
7d - 4w,
28  in surface water, scientific judgement based upon
  estimated unacclimated aerobic aqueous
  biodegradation half-life,
14  14d - 8w,
56  in ground water, scientific judgement based upon
  estimated unacclimated aerobic aqueous
  biodegradation half-life,
  Howard 1991
 
Aerobic degradation in water :
Aerobic half-life:
7d - 4w,
scientific judgement based upon aqueous aerobic screening test 
data for 1-chloropropane and 1-chlorobutane (Howard 1991).
 
Anaerobic degradation in water :
Anaerobic half-life:
28d - 16w,
scientific judgement based upon estimated unacclimated aerobic 
aqueous biodegradation half-life (Howard 1991).
 
Total degradation in water :
Biodegradation:
1% by BOD              1% by BOD 
period: 28d            period: 28d
substance: 1.84 mg/l   substance: 4.19 mg/l
sludge 2 mg/l          sludge: 2 mg/l 
(MITI 1992)
 
LC50 values to fishes, mg/l :
40  srv,act, 96 hr, Pimephales promelas,
  Phipps & Holcombe 1985
19  srv,act, 96 hr, Carassius auratus,
  Phipps & Holcombe 1985
36  srv,act, 96 hr, Salmo gairdneri,
  Phipps & Holcombe 1985

References
3120Howard, P.H., Boethling, R.S., Jarvis, W.F., Meylan, W.M. & Michalenko, E.M., Handbook of Environmental Degradation Rates, 1991. Lewis Publicers, Inc., Chelsea, Michigan, U.S.A., pp. 725.
3105MITI 1992. Biodegradation and bioaccumulation data of existing chemicals based on the CSCL Japan. Compild under the Safety Division Basic Industries Bureau Ministry of International Trade & Industry, Japan. Edited by Chemicals Inspection & Testing Institute, Japan.
1123Phipps, G.L. & Holcombe, G.W. 1985. A method for multiple species toxicant testing: acute toxicity of 10 chemicals to 5 vertebrates and 2 invertebrates. Environm. Pollut. (Ser A) 38: 141 - 157.
3104Sangster, J. 1989. Octanol-water partition coefficients of simple organic compounds. J. Phys. Chem. Ref. Data, Vol 18, No. 3: 1111 - 1229.
3030Yaws, C., Yang, H-C. & Pan, X. 1991. Henry's law constants for 362 organic compounds in water. Chemical Engineering. November. p 179 - 185.

 
 
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