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Data bank of environmental chemicals     |     The Finnish Environment Institute (SYKE)
 


24.4.2024

Data bank of environmental properties of chemicals


Chemical
Dibenz(a,h)anthracene
CAS-number :
53-70-3
 
Synonyms :
1,2:5,6-dibenzanthracene
 
Sumformula of the chemical :
C22H14 C22H14
EINECS-number :
2001818
 
Log octanol/water coefficient, log Pow :
6.75  Sangster 1989
 
Log soil sorption coefficient, log Kom :
6.31  observed, Sabljic 1987
6.44  calculated, Sabljic 1987
 
Photochemical degradation in air :
Atmospheric photolysis half-life: 
6hr - 782 hr, 
scienbtific judgement based upon measured rate of photolysis 
in heptane under November sunlight (High t1/2) and the above 
data adjusted by ratio of sunlight photolysis half-lives for
benz(a)anthracene in water vs. heptane (low t1/2)
(Howard 1991).

Photooxidation half-life in air: 
0.428hr - 4.28hr,
scientific judgement based upon estimated rate constant for
reaction with hydroxyl radical in air (Howard 1991).
 
Photochemical degradation in water :
Aquatic photolysis half-life: 
6hr - 782hr, 
scientific judgement based upon measured rate of photolysis in 
heptane under November sunlight (high t1/2) and the above data 
adjusted by ratio of sunlight photolysis half-lives for 
benz(a)anthracene in water vs. heptane (low t1/2) 
(Howard 1991).
 
Half-life in air, days :
0.02  0.428hr - 4.28hr,
0.18  scientific judgement based upon estimated
  photooxidation half-life in air,
  Howard 1991
 
Half-life in soil, days :
361  361d - 2.58yr, based upon aerobic soil
928.8  die-away test data,
  Howard 1991
 
Half-life in water, days :
0.25  6hr - 782hr,
32.58  in surface water, scientific judgement based
  upon sunlight photolysis half-life in water,
712.8  1.98yr - 5.15yr,
1854  in ground water, scientific judgement based
  upon estimated unacclimated aqueous aerobic
  biodegradation half-life,
  Howard 1991
 
Aerobic degradation in water :
Aerobic half-life:
361d - 2.58yr, based upon aerobic soil die-away test data
(Howard 1991).
 
Anaerobic degradation in water :
Anaerobic half-life:
3.96yr - 10.3yr, scientific judgement based upon estimated
unacclimated aqueous aerobic biodegradation half-life
(Howard 1991).
 
Other information of water organisms :
Lethal threshold concentration (LT50):
0.0004 mg/l, 0.13 d (Newsted & Giesy 1987).

References
3120Howard, P.H., Boethling, R.S., Jarvis, W.F., Meylan, W.M. & Michalenko, E.M., Handbook of Environmental Degradation Rates, 1991. Lewis Publicers, Inc., Chelsea, Michigan, U.S.A., pp. 725.
1889Newsted, J.L. & Giesy, J.P. 1987. Predictive models for photoinduced acute toxicity of polycyclic aromatic hydrocarbons to Daphnia magna, Strauss (Cladocera,Crustacea). Environ. Toxicol. Chem. 6: 445.
1973Pilli.A., Carle, D.O., Kline. E., Pickering. Q. & Lazorchak. J. 1988. Effets of pollution on freshwater organisms. JWPCF 60(6): 994 - 1065.
2324Sabljic, A. 1987. On the prediction of soil sorption coefficients of organic pollutants from molecular structure: application of molecular topology model. Environ. Sci. Technol. 21: 358 - 366.
3104Sangster, J. 1989. Octanol-water partition coefficients of simple organic compounds. J. Phys. Chem. Ref. Data, Vol 18, No. 3: 1111 - 1229.

 
 
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