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Data bank of environmental chemicals     |     The Finnish Environment Institute (SYKE)
 


11.5.2024

Data bank of environmental properties of chemicals


Chemical
Citric acid
CAS-number :
77-92-9
 
Synonyms :
2-hydroksi-1,2,3-propaanitrikarboksyylihappo
2-hydroxy-1,2,3-propanetricarboxylic acid
beta-hydroxytricarballylic acid
Sitruunahappo
 
Sumformula of the chemical :
C6H8O7
EINECS-number :
2010691
 
Molecular weight :
192.12
 
Spesicif gravity (water=1) :
1.542  at 18/4 °C
 
Water solubility, mg/l :
1330  cold
 
Melting point, °C :
153 
 
Log octanol/water coefficient, log Pow :
-1.72  Verschueren 1983
 
Other physicochemical properties :
Decomposes.
 
Effects on microorganisms :
Toxicity threshold (cell multiplication inhibition test):
Pseudodomonas putida >10 000 mg/l. 
(Bringmann & Kühn 1980)
 
LOEC values to algae, mg/l :
80  rpd, schr, Microcystis aeruginosa
  Bringmann & Kühn 1976
 
Other information of water organisms :
LC100, 120 mg/l, act, Daphnia magna (Ellis 1937).

Toxicity threshold (cell multiplication inhibition test):
Microcystis aeruginosa     80 mg/l  (Bringmann & Kühn 1976)
Scenedesmus quadricauda   640 mg/l  (Bringmann & Kühn 1980a)
Entosiphon sulcatum       485 mg/l  (Bringmann & Kühn 1980a)
Uronema parduczi Chatton- 622 mg/l  (Bringmann & Kühn 1980b)
Lwoff

LD0, 80 mg/l, Daphnia magna, long time exposure in solf water. 
LD100, 120 mg/l, Daphnia magna, long time exposure in soft
water. 
(Verschueren 1983)

Carassius auratus: period of survival:
                   4-48 hr: 894 ppm at pH 4.0
                   days: 625 ppm at pH 4.5 (Verschueren 1983)

LD0, 625 mg/l, Carassius auratus, long time exposure in hard
water.

LD100, 894 mg/l, Carassius auratus, long time exposure in hard
water. 
(Verschueren 1983)

References
187Bringmann, G. & Kühn, R. 1976. Vergleichende Befunde der Schadwirkung wassergefährdender Stoffe gegen Bakterien (Pseudomonas putida) und Blaualgen (Microcystis aeruginosa). Gwf-Wasser-Abwasser 117(9).
188Bringmann, G. & Kühn, R. 1980a. Comparison of the toxicity thresholds of water pollutants to bacteria, algae and protozoa in the cell multiplication inhibition test. Water Res. 14: 231 - 241.
189Bringmann, G. & Kühn, R. 1980b. Bestimmung der biologischen Schadwirkung wassergefahrdender Stoffe gegen Protozoen. II. Bakterienfressende Ciliaten, Z. Wasser/Abwasser Forsch. 1: 26 - 31.
400Ellis, M.M. 1937. Detection and measurement of stream pollution, U.S. Bur. Fisheries Bull. No 22, XLVIII: 365 - 437. U.S. Dept. Commerce, Washington.
704Kemp, H.T., Little, R.L., Holoman, V.L. & Darby, R.L. 1973. Water quality data book - Vol. 5. Effects of chemicals on aquatic life. EPA. Water pollution control research series 09/73.
1468Verschueren, K. 1983. Handbook of environmental data of organic chemicals. Van Nostrand Reinhold Co. Inc., New York. 1310 s.

 
 
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